Molecular Understanding of Diffusion in Confinement
نویسندگان
چکیده
منابع مشابه
Molecular understanding of diffusion in confinement.
We introduce a computational method to directly relate diffusivities to the microscopic behavior of the adsorbed molecules. We apply this method to gases in an MFI-type molecular sieve, the reference system in this field. Transitions in the number and nature of adsorption sites result in temporary local increases in the diffusion. This occurs at different loadings in each of the x, y, and z dir...
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ژورنال
عنوان ژورنال: Physical Review Letters
سال: 2005
ISSN: 0031-9007,1079-7114
DOI: 10.1103/physrevlett.95.164505